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![]() Thus boron has 4 effective pairs, which requires sp 3-hybridization. ![]() It's Lewis Structure, and it's 3-D Molecular Geometry (Shape) are shown below:įrom above, we see that the BF 4 - ion has a tetrahedral molecular geometry. It has 10 valence electrons, and both the carbon and the oxygen are sp-hybridized.Īs we saw with N 2, the C≡O triple bond contains one sigma bond (σ-bond) because there's two sp-orbitals, and two pi bonds (π-bonds) from both the carbon's and the oxygen's two 2p atomic orbitals.Ĭ. " s.p1.p2.p3.d1.d2 " (sound 'em out as you count).Įx: For each of the following molecules or ions, predict the hybridization of each atom, and completely describe the molecular structure.Ī. * TIP - Just count the effective pairs around each atom like this: ➞ this allows us to properly draw its Lewis Structure and here we go: ➞ if we can get the Lewis Structure, we can answer the question. Two effective pairs ➞ sp-hybridization for N 2Īs mentioned above, the N≡N triple bond contains one sigma bond (σ-bond) because there's two sp-orbitals, and two pi bonds (π-bonds) from each nitrogen's two 2p atomic orbitals.Įx: Determine the hybridization of each iodine atom in the following anion: I 3. The moleculary geometry is "linear," which has an arrangement of 2 effective pairs around each nitrogen atom. ➞ this allows us to properly draw its Lewis Structure and determine its Molecular Geometry: linear. ➞ we first need to figure out that N 2 has 10 valence electrons. □Įx: Completely describe the bonding in N 2 Hydrogen keeps its original 1s atomic orbital. This requires sp 3-hybridization for NH 3 Now that we have its three-dimensional geometry, we can see there's 4 effective pairs around the central nitrogen atom. ➞ this allows us to properly draw its Lewis Structure and determine its Molecular Geometry: trigonal pyramidal. ➞ we first need to figure out that NH 3 has 8 valence electrons. ![]() The sp 3 Hybridization of NH 3Įx: Completely describe the bonding in NH 3 ![]() Today we're going to do a bunch of hybridization examples and hybrid orbital practice problems. If you missed my first two videos on types of hybridization and hybrid orbitals, you might want to watch them before continuing here. #HYBRID ATOMIC ORBITALS FREE#3 - Chemical Quantities and StoichiometryĤ - Types of Chemical Reactions and Solution Stoichiometryħ - Quantum Mechanical View of the Atom, and Periodicityĩ - Covalent Bonding and Molecular Orbitalsġ0 - Liquids, Solids, and Intermolecular Forcesġ5 - Applications of Acid-Base Equilibriaġ6 - Spontaneity, Entropy, and Free Energyġ8 - Transition Metals and Coordination ChemistryĢ0 - An Introduction to Organic Chemistryġ - Structural, Bonding, Molecular PropertiesĢ - The Nature of Organic Compounds: Alkanes and Cycloalkanesģ - Stereochemistry of Alkanes and Cycloalkanes: 3-D Structures of MoleculesĤ - The Study of Organic Reactions: An Overviewġ0 - Substitution (SN2, SN1) and Elimination (E2, E1) Reactionsġ1 - Mass Spectrometry and IR Spectroscopyġ3 - Conjugated Systems and UV Spectroscopyġ5 - Electrophilic Aromatic Substitution (E.A.S.)ġ8 - Aldehydes and Ketones: Nucleophilic Addition ReactionsĢ0 - Carboxylic Acid Derivatives and Nucleophilic Acyl Substitution ReactionsĢ1 - Carbonyl Alpha-Substitution Reactions ![]() ![]() ![]() ipynb specification document file-composed of narrative text, code cells, and outputs. Here are several aspects to know about Jupyter Notebooks: Jupyter Notebooks provides a document specification and a graphical user interface for editing documents.
![]() ![]() Third, the CDC team also looked at similar flu-surveillance data from five other site across the U.S. It only means that if it was circulating, it was at such low levels that it could not be detected even when testing 5,000 specimens from people with respiratory illness.” “That doesn’t mean the virus wasn’t present anywhere in the community. 20 “showed no evidence of COVID-19 infection,” Butler says. More than 5,000 samples from this study collected from people with respiratory symptoms from Jan. Those came from people who were participating in the Seattle Flu Study to monitor for flu prevalence, and provided samples from the nose and back of the throat which could be re-analyzed for SARS-CoV-2. That conclusion is supported by another set of tests on specimens collected from nasal passages from people in the Seattle area, where the first U.S. case was identified in Washington state other cases identified in the area shared similar genetic signatures. Based on the these sequences, which serve as a type of genetic fingerprint for tracing different strains and lineages of the virus, the researchers believe there was one virus lineage introduced from China in late January, when the first confirmed U.S. and elsewhere also suggest that the virus wasn’t spreading widely in the U.S. Second, genetic sequences of the SARS-CoV-2 virus in the U.S. The 14 counties the agency focused on included those that ended up having early community-based cases and likely were among the first regions to have spread of the disease. Those data, part of the National Syndromic Surveillance Program, include 4,000 health care facilities in 47 states who report information on emergency room visits. First, he says, emergency room data from 14 counties across the country did not show an uptick in some of the hallmark symptoms of the disease, including fever, cough and difficulty breathing, until Feb. earlier than late January, but didn’t spread until then. Jay Butler, the CDC’s deputy director for infectious diseases head of the agency’s COVID-19 response and a co-author of the recent paper, highlights four lines of evidence to support idea that COVID-19 was in the U.S. But COVID-19 tests developed by the CDC were also delayed because of early contamination issues, which meant that public health officials were behind in identifying those who were infected.ĭr. government initially screened passengers arriving from infection hot spots in China in mid-January before stopping arrivals from the country altogether several weeks later. ![]() ![]() ![]() (Opens in a new window)Īuthy and Google Authenticator both build on TOTP, and in fact you can use Authy on any site that supports Google Authenticator. Since 1982, PCMag has tested and rated thousands of products to help you make better buying decisions. #Authy desktop client passwordA malefactor who somehow plucks that one-time password out of the ether will find it useless within 30 seconds. You log in using your regular password, then enter the current one-time password from your device, and you're in. By convention, each TOTP is good for 30 seconds. Both the device and the server can generate a time-based one-time password by processing that key along with the current time. When the user registers a TOTP-supporting device with a secure website, a unique shared key is created. In 2011, the Internet Engineering Task Force released a standard for Time-based One-Time Passwords (TOTP) (Opens in a new window). A hacker who steals or guesses your password will be foiled by the authentication step that requires that token. Authy turns your smartphone into a physical token that's needed for login, along with the password. A password manager lets you use tough-to-remember passwords, but in a data breach it doesn't matter if your password was "* " or "password." You can vastly enhance your security by using a two-factor authentication scheme, and Twilio's Authy makes two-factor authentication easier than ever.Įxperts divide authentication factors into three types: something you know (a password, for example), something you have (a physical object), and something you are (a fingerprint or other biometric trait). Desktop edition does not force use of a master password.Ī password is a terrible way to protect an online account, because anybody who learns your password owns the account, even if they're half a world away. #Authy desktop client how to
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![]() The popularity of Saturnalia ensued until the 3rd and 4th centuries AD. The famous Rockefeller Center Christmas Tree in New York City This notion is further seen in the later celebration (during the Roman Empire) of the Dies Natalis of Sol Invictus: “Birthday of the Unconquerable Sun,” on December 25. Macrobius describes the Saturnalia almost as a festival of lights leading up to the winter solstice (Dec. While, Seneca, Horace, Catullus, and the Calendar of Philocalus prove to be excellent sources the best source comes from the multivolume work of Macorbius. … Were you here, I would willingly confer with you as to the plan of our conduct whether we should eve in our usual way, or, to avoid singularity, both take a better supper and throw off the toga. Loose reins are given to public dissipation everywhere you may hear the sound of great preparations, as if there were some real difference between the days devoted to Saturn and those for transacting business. It is now the month of December, when the greatest part of the city is in a bustle. (Seneca, Ad Lucilium Epistulae Morales 18.1-2) Si te hic haberem, libenter tecum conferrem, quid existimares esse faciendum: utrum nihil ex cotidiana consuetudine movendum an, ne dissidere videremur cum publicis moribus, et hilarius cenandum et exuendam togam. Adeo nihil interest, ut non videatur 1 mihi errasse, qui dixit olim mensem Decembrem fuisse, nunc annum. Ingenti apparatu sonant omnia, tamquam quicquam inter Saturnalia intersit et dies rerum agendarum. The following was found in a letter to a friend.ĭecember est mensis cum maxime civitas sudat. However from the late Republic and onwards, their presence in socially situations became more frequent. In the Republic, a woman presence in such debauchery would be unseemly. The participation of freeborn Roman women (in comparison to slave women, who would be participating) depended on the custom of the time. Slaves were not allowed to wear this “freed” cap, but for the Saturnalia everyone wore them so that there was not class distinction. The pilleus is a cone like felt cap that usually denotes the stature of a freedman (a slave who is freed by their master, but not quite a citizen). While quotidian, Roman citizens went about bare-headed during Saturnalia they worn the pilleus. Instead, the Greek clothing known as synthesis was adopted. The toga, which the iconic dress for all respectable Roman citizen, was discarded for this day. Ancient Greek red-figure plate from Apulia, third quarter of the 4th century BC, Louvre. ![]() ![]() Fruits, plants, insects, small invertebrates. Uses tail as "fifth limb" to help grasp limbs in trees. Tropical rain forests to woodland savanna and grasslands in Africa. Chimps communicate in a manner similar to human nonverbal communication, using vocalizations, hand gestures, and facial expressions.Ĭomparison between Monkey and Chimpanzee:Ĭallitrichidae (e.g., marmosets) and Cebidae (e.g., squirrel monkeys)Īfrica, Asia, and Central and South America. They are known to use stones as hammers, sticks to fish out termites, complex nest building, etc. Chimps show an increase in tool use, a sign of higher intelligence. Female chimpanzees will show compliance to the alpha male by presenting their hindquarters. Lower-ranking chimpanzees will show respect by submissively gesturing in body language or reaching out their hands while grunting. They also lack a tail and have testicles that are unusually large for their bodies.Ĭhimps live in communities of multiple male and female groups with an alpha male. Chimps have a dark coats and no hair on their face, fingers, palms of the hands, and soles of the feet. Both the common chimpanzee and bonobo can walk upright on two legs when carrying objects with their hands and arms. The bonobo is slightly shorter and thinner than the common chimpanzee but has longer limbs.īoth the species are known for climbing trees and walking both, on fours as well as twos. They have long arms, which are longer than their legs and when extended, span one and a half times the body’s height. Chimps are often believed to share similarities in DNA with the human and are considered as the closest relatives to human beings.Ĭhimps are similar in heights to humans, with average male chimp standing up to 1.7 m (5.6 ft) high and weigh as much as 70 kg, while the female is usually smaller and lighter. Chimpanzees are the only known members of the subtribe Panina. They are more prone to running on branches and climbing to the top of the treetops.Ĭhimpanzees have two different subspecies: the common chimpanzee and Bonobo. Monkeys cannot swing from tree to tree as popularly believed, their arm structures do not support this behavior, and rather they run across the branches. Monkeys have small arms and long legs and opposable thumbs on both their hands and legs. Monkeys posses a smaller brain and have a diet of fruits, vegetables and small insects. They show affection and make peace by grooming each other. They also communicate via expressions, vocalizations and body movements. Monkeys can be arboreal, as well as ground dwellers, which means that they can live in trees or built nests on the ground. Monkeys are also often small in size with the smallest being 4.6 inches with a 6.8 inches tail, weighing 100 grams to 3.3 feet weighing 36 kilograms. Chimps actually belong to the Ape family, which differs from the monkeys greatly.Ī simple way to distinguish the monkeys from apes is to check for a tail monkeys have tails and apes do not, which means that chimps do not have a tail. Monkeys and chimps, although initially believed to be similar in species resulted to belong to complete differ scientific family. There are more 260 living species of monkeys, many of which are arboreal. Monkeys are primates that belong to the Haplorhini suborder and Simiiformes infraorder. Monkeys can be divided into two groups: Old World monkeys and New World monkeys, excluding apes and humans. Chimpanzees split from the human branch of the family about four to six million years ago. While, both monkeys and chimps are primates, they both belong to families.Ĭhimpanzees or chimps, are actually the closest relatives to the humans, with only a 5% difference in the DNA. The famous Curious George is actually a chimp, and is wrongly referred to as a monkey. To many untrained eyes, monkeys and chimpanzees can seem similar to the point they are even used in literature wrong. Monkeys and Chimpanzees are often confusing for many people because of their similar looks. Chimps actually belong to the Ape family, which differs from the monkeys greatly. Key Difference: Monkeys and chimps, although initially believed to be similar in species resulted to belong to complete differ scientific family. ![]() ![]() ![]() ![]() This British book has great photos and lists Elton’s albums in a really picturesque manner. I have some from the seventies about Elton John and Bernie Taupin. ![]() This book is joyful on the way the b A wonderful fan book like I used to collect as a kid on my favorite music and TV/Film stars. Albums were the most important and we analyzed how they were put together and the total quality of the music in them. Listing the albums is really important because that’s the way we saw music during his heyday. This is the ultimate keepsake for all Elton John fans.moreĪ wonderful fan book like I used to collect as a kid on my favorite music and TV/Film stars. Fully illustrated throughout, with rare archival memorabilia and previously unpublished photographs, this book covers everything from his childhood as a piano prodigy in the London suburb of Pinner through his early days playing West End gigs and his fortuitous meeting-and subsequent lifelong partnership-with lyricist Bernie Taupin and the song that started it all, “Your Song,” to John’s meteoric rise to stardom, his challenges along the way, and his tireless work for various charities, including the Elton John AIDS Foundation. Just in time for his farewell world tour, this lavish, unofficial retrospective commemorates John’s incredible life and career. One of the most prolific and commercially successful, and beloved, musical artists of all time, Elton John has won six Grammy Awards and sold more than 300 million records during a career spanning over half a century: his Candle In the Wind 1997 remains the bestselling single in history. #Elton john rocket man movie#One of the most prolific and commercially successful, and beloved “Still up for more Elton after the movie and the memoir? This in-depth retrospective is just the thing.” - People magazine featured as one of the year’s “Best New Coffee-Table Books.”Ī celebratory retrospective of one of popular music’s most enduring and beloved stars, as he tours the world one last time. “Still up for more Elton after the movie and the memoir? 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